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Russian Chemical Reviews, 2025, Volume 94, Issue 2, RCR5156
DOI: https://doi.org/10.59761/RCR5156
 

Prospects for the development of materials based on high-entropy oxides, carbides, and oxycarbides stable at high temperatures

V. L. Stolyarovaab, I. I. Vasilevab, V. A. Vorozhtcovb, T. V. Sokolovab

a Saint Petersburg State University, St. Petersburg, Russian Federation
b Branch of Petersburg Nuclear Physics Institute named after B.P Konstantinov of National Research Center "Kurchatov Institute" — I.V. Grebenshchikov Institute of Silicate Chemistry, St. Petersburg, Russia
Abstract: The importance of high-entropy materials is dictated by the requirements of high-temperature technologies related to the problems of aviation and aerospace engineering, nuclear power engineering, metallurgy, and microelectronics. The significant interest in the materials mentioned is explained by a combination of unique physical and chemical properties such as high mechanical strength and hardness and chemical and thermal stability. This review gives analysis of studies that address the physicochemical properties of high-entropy oxides, carbides, and oxycarbides at high temperatures and illustrates the potential use of these results for the synthesis and operation of a broad range of materials under high-temperature treatment. It is shown that the search for optimal solutions for the development of refractory materials based on multicomponent oxides, carbides, and oxycarbides requires the use of integrated physicochemical approach, involving information on the thermodynamic properties, phase equilibria, and vaporization processes.
The bibliography includes 247 references.
Keywords: high-entropy materials, high temperatures, high-entropy oxide systems, high-entropy carbide systems, high-entropy oxycarbide systems, thermodynamic, modelling.
Received: 02.11.2024
Document Type: Article
Language: English
Original paper language: Russian


Citation: V. L. Stolyarova, I. I. Vasileva, V. A. Vorozhtcov, T. V. Sokolova, “Prospects for the development of materials based on high-entropy oxides, carbides, and oxycarbides stable at high temperatures”, Usp. Khim., 94:2 (2025), RCR5156; Russian Chem. Reviews, 94:2 (2025), RCR5156
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