Abstract:
In recent years, research dealing with organic paramagnetic compounds such as stable radicals and high-spin systems has been focused on applied aspects. Several key trends have formed in the application and, hence, in the function-oriented synthesis of organic radicals and polyradicals. This review addresses one of such trends in which the dominant role is played by so-called conjugated nitroxides. Their specific feature is the presence of any unsaturated moiety (C=C, C=N or C=O multiple bond; aromatic or heteroaromatic ring; fused polyaromatic system) adjacent to the nitroxide group. The achievements of the chemistry of conjugated nitroxides are presented, and their physicochemical properties, magneto-structural correlations and practical applications are discussed.
The bibliography includes 641 references.
Keywords:
organic paramagnets, nitroxide radicals, hybrid phenoxyl-nitroxides, unpaired electron delocalization, electrochemistry, high-spin systems, molecular magnetism, quantum-chemical calculations, parameters of the Hamiltonian spin, theoretical prediction of magnetic motives, structure-property correlations.
Citation:
E. V. Tretyakov, V. I. Ovcharenko, A. O. Terent'ev, I. B. Krylov, T. V. Magdesieva, D. G. Mazhukin, N. P. Gritsan, “Conjugated nitroxides”, Russian Chem. Reviews, 91:2 (2022), RCR5025
S. V. Fokin, G. V. Romanenko, K. A. Smirnova, A. S. Bogomyakov, A. A. Serykh, E. V. Tretyakov, J Struct Chem, 66:1 (2025), 63
Ekaterina N. Kudryavtseva, Darina I. Nasyrova, Alexander A. Korlyukov, Evgeny M. Kadilenko, Nina P. Gritsan, Debin Xia, Evgeny V. Tretyakov, ACS Omega, 2025
Igor A. Zayakin, Galina V. Romanenko, Alexander A. Korlyukov, Evgeny V. Tretyakov, Organometallics, 2025
Muhammad Shehzad Sultan, Vladimir I. Makarov, Frank Mendoza, Muhammad Sajjad, Danilo G. Barrionuevo Diestra, Flavia P. N. Inbanathan, Eli Skelton, Uvinduni I. Premadasa, Katherine Leslee A. Cimatu, Khaled Habiba, Wojciech M. Jadwisienczak, Brad R. Weiner, Gerardo Morell, Journal of Applied Physics, 135:8 (2024)
Pavel V. Petunin, Evgeny V. Tretyakov, Matvey K. Shurikov, Daria E. Votkina, Galina V. Romanenko, Alexey A. Dmitriev, Nina P. Gritsan, Daniil M. Ivanov, Rosa M. Gomila, Antonio Frontera, Giuseppe Resnati, Vadim Yu. Kukushkin, Pavel S. Postnikov, Crystal Growth & Design, 24:5 (2024), 2104
Irina V. Golomolzina, Svyatoslav E. Tolstikov, Kristina A. Smirnova, Sergey V. Fokin, Gleb A. Letyagin, Galina V. Romanenko, Artem S. Bogomyakov, Chemistry A European J, 30:13 (2024)
S. V. Fokin, E. T. Chubakova, S. E. Tolstikov, G. V. Romanenko, K. A. Smirnova, A. S. Bogomyakov, V. I. Ovcharenko, J Struct Chem, 65:2 (2024), 230
Evgeny V. Tretyakov, Igor A. Zayakin, Alexey A. Dmitriev, Matvey V. Fedin, Galina V. Romanenko, Artem S. Bogomyakov, Anna Ya. Akyeva, Mikhail A. Syroeshkin, Naoki Yoshioka, Nina P. Gritsan, Chemistry A European J, 30:8 (2024)
I. V. Fedyanin, A. I. Samigullina, E. V. Tretyakov, J Struct Chem, 65:3 (2024), 619
I. A. Zayakin, M. A. Syroeshkin, P. G. Shangin, A. A. Korlyukov, A. A. Dmitriev, N. P. Gritsan, E. V. Tretyakov, Russ Chem Bull, 73:5 (2024), 1216
Igor A. Zayakin, Pavel V. Petunin, Pavel S. Postnikov, Alexey A. Dmitriev, Nina P. Gritsan, Pavel Dorovatovskii, Alexander Korlyukov, Matvey V. Fedin, Artem S. Bogomyakov, Anna Ya. Akyeva, Roman A. Novikov, Pavel G. Shangin, Mikhail A. Syroeshkin, Julia V. Burykina, Evgeny V. Tretyakov, J. Am. Chem. Soc., 146:19 (2024), 13666
Igor A. Zayakin, Ivan V. Kurganskii, Ashok Keerthi, Martin Baumgarten, Alexey A. Dmitriev, Nina. P. Gritsan, Svyatoslav E. Tolstikov, Renad Z. Sagdeev, Alexander A. Korlyukov, Evgeny V. Tretyakov, Matvey V. Fedin, Appl Magn Reson, 2024
Citation in format AMSBIB
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