Abstract:
Many paramagnetic metal complexes have emerged as unique magnetic materials (single-molecule magnets), which behave as conventional magnets at the single-molecule level, thereby making it possible to use them in modern devices for data storage and processing. The rational design of these complexes, however, requires a deep understanding of the physical laws behind a single-molecule magnet behaviour, the mechanisms of magnetic relaxation that determines the magnetic properties and the relationship of these properties with the structure of single-molecule magnets. This review focuses on the physical methods providing such understanding, including different versions and various combinations of magnetometry, electron paramagnetic and nuclear magnetic resonance spectroscopy, optical spectroscopy and X-ray diffraction. Many of these methods are traditionally used to determine the composition and structure of new chemical compounds. However, they are rarely applied to study molecular magnetism.
The bibliography includes 224 references.
Keywords:
Electron paramagnetic resonance spectroscopy, magnetic anisotropy, magnetometry, molecular design, molecular magnetism, nuclear magnetic resonance spectroscopy, optical spectroscopy, single-molecule magnets, X-ray diffraction.
Citation:
V. V. Novikov, Yu. V. Nelyubina, “Modern physical methods for the molecular design of single-molecule magnets”, Russian Chem. Reviews, 90:10 (2021), 1330–1358
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\by V.~V.~Novikov, Yu.~V.~Nelyubina
\paper Modern physical methods for the molecular design of single-molecule magnets
\jour Russian Chem. Reviews
\yr 2021
\vol 90
\issue 10
\pages 1330--1358
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Linking options:
https://www.mathnet.ru/eng/rcr4361
https://doi.org/10.1070/RCR5002
https://www.mathnet.ru/eng/rcr/v90/i10/p1330
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