Abstract:
The main achievements and development trends of the past 107–15 years related to the catalytic cyclopropanation of unsaturated compounds with diazomethane are integrated and analyzed. The attention is focused on the most efficient catalysts based on palladium compounds. Data on the effects of substrate structure and nature of catalyst components on the regio- and stereoselectivity of these reactions are systematized. Characteristic features of safe methods for diazomethane generation are considered, including the use of membrane technologies and continuous-flow and in situ preparation methods, which have prospects for industrial application.
The bibliography includes 281 references.
Citation:
L. G. Menchikov, E. V. Shulishov, Yu. V. Tomilov, “Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane”, Russian Chem. Reviews, 90:2 (2021), 199–230
\Bibitem{MenShuTom21}
\by L.~G.~Menchikov, E.~V.~Shulishov, Yu.~V.~Tomilov
\paper Recent advances in the catalytic cyclopropanation of unsaturated compounds with diazomethane
\jour Russian Chem. Reviews
\yr 2021
\vol 90
\issue 2
\pages 199--230
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\crossref{https://doi.org/10.1070/RCR4982}
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Linking options:
https://www.mathnet.ru/eng/rcr4331
https://doi.org/10.1070/RCR4982
https://www.mathnet.ru/eng/rcr/v90/i2/p199
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