Abstract:
The review is devoted to the application of $C_2$-symmetric diamines and their derivatives as organocatalysts for asymmetric reactions (aldol, Michael, Mannich, Diels–Alder reactions, desymmetrization, allylation, etc.). Amino acid derivatives, di- and polyamides (sulfamides), bisureas, bisthioureas, bisamidines and bisguanidines are considered. Significant attention is given to the effect of the catalyst structure on the mechanism of catalytic action. Successful applications of such catalysts in enantioselective synthesis of chiral biologically active compounds are summarized.
The bibliography includes 181 references.
Received: 23.03.2015
Bibliographic databases:
Document Type:
Article
Language: English
Original paper language: Russian
Citation:
S. G. Zlotin, S. V. Kochetkov, “$C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis”, Russian Chem. Reviews, 84:11 (2015), 1077–1099
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\by S.~G.~Zlotin, S.~V.~Kochetkov
\paper $C_2$-symmetric diamines and their derivatives as promising organocatalysts for asymmetric synthesis
\jour Russian Chem. Reviews
\yr 2015
\vol 84
\issue 11
\pages 1077--1099
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\crossref{https://doi.org/10.1070/RCR4562}
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Linking options:
https://www.mathnet.ru/eng/rcr4075
https://doi.org/10.1070/RCR4562
https://www.mathnet.ru/eng/rcr/v84/i11/p1077
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