Abstract:
The potentialities of radical cage reactions as a tool for investigating the chemical structures of polymers are considered. The kinetic regularities of triplet carbene reactions in the matrix-isolated state and in clusters are analysed to reveal structural features of the cage surroundings. The possibility of determination of structural characteristics of filled polymers from kinetic data is discussed. The bibliography includes 103 references.
Received: 16.05.2000
Bibliographic databases:
Document Type:
Article
UDC:
541(64+127):541.1
Language: English
Original paper language: Russian
Citation:
E. Ya. Davydov, A. P. Vorotnikov, V. P. Pustoshnyi, G. B. Pariiskii, “Application of radical cage reactions in studies of microstructures of polymers and composites”, Usp. Khim., 69:10 (2000), 981–992; Russian Chem. Reviews, 69:10 (2000), 899–909
Linking options:
https://www.mathnet.ru/eng/rcr1548
https://doi.org/10.1070/RC2000v069n10ABEH000604
https://www.mathnet.ru/eng/rcr/v69/i10/p981
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