A. D. Garnovskii, D. A. Garnovskii, I. S. Vasil'chenko, A. S. Burlov, A. P. Sadimenko, I. D. Sadekov, “Competitive coordination: ambident ligands in the modern chemistry of metal complexes”, Usp. Khim., 66:5 (1997), 434–462; Russian Chem. Reviews, 66:5 (1997), 389

Abstract: Data on the problem of competitive coordination, obtained mainly during the last 10 years, are surveyed and treated systematically. The competitive binding of metals in complexes of bi- and poly-dentate ligand systems — simple diatomic and triatomic compounds (N₂, O₂, CO, CO₂, CS₂, etc.), ambident anions (CN^-, NCX^-, NO₂^-, SO₃^2-, etc.), and neutral aliphatic, aromatic, and heterocyclic compounds, including chelating organic ligands — is examined. Attention is specially concentrated on nontraditional ways in which typical ligand systems are coordinated and on regioselective synthesis as a method for the specific synthesis of metal complexes with a specified location of the coordinate bond. The bibliography includes 575 references.

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