Abstract:
The addition of amino acid esters to [2-B10H9–N≡CMe]− Bu4N+ salt under mild conditions affords amidine closo-decaborates in high yields. The structure of compound (PPh4)[2-B10H9NH=C(Me)NHCH2COOEt] was elucidated by single-crystal XRD analysis.
Citation:
A. V. Nelyubin, I. N. Klyukin, A. S. Novikov, A. P. Zhdanov, M. S. Grigoriev, K. Yu. Zhizhin, N. T. Kuznetsov, “Nucleophilic addition of amino acid esters to nitrilium derivatives of closo-decaborate anion”, Mendeleev Commun., 31:2 (2021), 201–203
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https://www.mathnet.ru/eng/mendc878
https://www.mathnet.ru/eng/mendc/v31/i2/p201
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