Abstract:
A 1: 1 photostable complex between dichlorosilylene and CO2 was detected using matrix-isolation FTIR spectroscopy. The photostability can be attributed to the existence of photochemical equilibria between this complex and products of its isomerization, first of all, a complex of dichlorosilanone with CO, which are strongly shifted to the complex. A detailed computational study of the potential energy surface of the SiCl2+CO2 system was carried out.
Citation:
S. E. Boganov, V. M. Promyslov, P. G. Shangin, M. A. Syroeshkin, M. P. Egorov, “Interaction of SiCl2 with CO2 in Ar matrices”, Mendeleev Commun., 31:2 (2021), 149–153
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https://www.mathnet.ru/eng/mendc862
https://www.mathnet.ru/eng/mendc/v31/i2/p149
This publication is cited in the following 5 articles:
M. P. Egorov, V. P. Ananikov, E. G. Baskir, S. E. Boganov, V. I. Bogdan, A. N. Vereshchagin, V. A. Vil', I. L. Dalinger, A. D. Dilman, O. L. Eliseev, S. G. Zlotin, E. A. Knyazeva, V. M. Kogan, L. O. Kononov, M. M. Krayushkin, V. B. Krylov, L. M. Kustov, V. V. Levin, B. V. Lichitsky, M. G. Medvedev, N. E. Nifantiev, O. A. Rakitin, A. M. Sakharov, I. V. Svitanko, G. A. Smirnov, A. Yu. Stakheev, M. A. Syroeshkin, A. O. Terent'ev, Yu. V. Tomilov, E. V. Tretyakov, I. V. Trushkov, L. L. Fershtat, V. A. Chaliy, V. Z. Shirinian, “Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences”, Russ Chem Bull, 73:9 (2024), 2423
Rui Fausto, Timur Nikitin, Bernardo A. Nogueira, Photochemistry, 2023, 66
Sergey E. Boganov, Rosa Becerra, Vladimir M. Promyslov, Pavel G. Shangin, Andrey V. Lalov, Mikhail P. Egorov, Robin Walsh, “Photoinduced reaction of dichlorosilylene with acetylene: Matrix isolation FTIR spectroscopic study”, Journal of Organometallic Chemistry, 962 (2022), 122270
S. E. Boganov, V. M. Promyslov, A. V. Lalov, M. A. Syroeshkin, M. P. Egorov, “Nonclassical complex of dichlorosilylene with CO: direct spectroscopic detection”, Russ Chem Bull, 70:6 (2021), 1084
Yu. V. Tomilov, L. G. Menchikov, E. A. Shapiro, V. D. Gvozdev, K. N. Shavrin, N. V. Volchkov, M. B. Lipkind, M. P. Egorov, S. E. Boganov, V. N. Khabashesku, E. G. Baskir, “Carbenes, related intermediates, and small-sized cycles: contribution from Professor Nefedov's laboratory”, Mendeleev Commun., 31:6 (2021), 750–768
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