Abstract:
For the first time, single crystal of Li2W0.96Mo0.04O4 has been grown by low-temperature-gradient Czochralski technique. The thermodynamic characteristics (standard formation enthalpy and lattice enthalpy) that are necessary to improve the growth technology have been studied by solution calorimetry. For Li2W1–xMoxO4 single crystals, correlations of lattice enthalpies and standard formation enthalpies with tolerance factor were found.
Citation:
N. I. Matskevich, V. N. Shlegel, A. N. Semerikova, V. D. Grigorieva, I. V. Korolkov, E. N. Tkachev, “Crystal growth and thermodynamic properties of lithium tungstate doped by 4% molybdenum”, Mendeleev Commun., 32:6 (2022), 834–836
Linking options:
https://www.mathnet.ru/eng/mendc815
https://www.mathnet.ru/eng/mendc/v32/i6/p834
This publication is cited in the following 2 articles:
N.I. Matskevich, A.N. Semerikova, V.A. Trifonov, D.V. Kochelakov, I.V. Korolkov, V.N. Shlegel, M.Yu. Matskevich, O.I. Anyfrieva, “Low-temperature-gradient Czochralski crystal growth, standard formation enthalpy and lattice enthalpy of cesium dimolybdate”, Journal of Solid State Chemistry, 325 (2023), 124143
N. I. Matskevich, V. D. Grigorieva, A. N. Semerikova, V. N. Shlegel, M. Yu. Matskevich, O. I. Anyfrieva, “Thermodynamic characteristics of sodium ditungstate single crystal”, Mendeleev Commun., 33:4 (2023), 522–524
Contact us: