Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane – air mixtures
Abstract:
Using the combustion of n-pentane – air mixtures as an example, it was shown that thermoacoustic regimes of ignition disappear in the presence of a platinum surface, which generates catalytic centers propagating into the volume. Thus, the platinum catalyst eliminates a certain stage of kinetic mechanism, and the negative temperature coefficient phenomenon vanishes. In the presence of a palladium catalytic surface that does not generate catalytic centers propagating into the volume, the phenomenon of a negative temperature coefficient occurs.
Keywords:
ignition, premixed, n-pentane–air, thermoacoustic, platinum, palladium, negative temperature coefficient.
Citation:
N. M. Rubtsov, G. I. Tsvetkov, V. I. Chernysh, K. Ya. Troshin, “Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane – air mixtures”, Mendeleev Commun., 32:5 (2022), 693–696