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Mendeleev Communications, 2022, Volume 32, Issue 5, Pages 693–696
DOI: https://doi.org/10.1016/j.mencom.2022.09.043
(Mi mendc771)
 

Communications

Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane – air mixtures

N. M. Rubtsova, G. I. Tsvetkova, V. I. Chernysha, K. Ya. Troshinb

a A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: Using the combustion of n-pentane – air mixtures as an example, it was shown that thermoacoustic regimes of ignition disappear in the presence of a platinum surface, which generates catalytic centers propagating into the volume. Thus, the platinum catalyst eliminates a certain stage of kinetic mechanism, and the negative temperature coefficient phenomenon vanishes. In the presence of a palladium catalytic surface that does not generate catalytic centers propagating into the volume, the phenomenon of a negative temperature coefficient occurs.
Keywords: ignition, premixed, n-pentane–air, thermoacoustic, platinum, palladium, negative temperature coefficient.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (460.1 Kb)


Citation: N. M. Rubtsov, G. I. Tsvetkov, V. I. Chernysh, K. Ya. Troshin, “Influence of noble metals on thermoacoustic oscillations and boundaries of the region of negative temperature coefficient during combustion of n-pentane – air mixtures”, Mendeleev Commun., 32:5 (2022), 693–696
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