Abstract:
1D coordination polymers [Cu2I2(AsPh3)2(L)]n (L = 4,4'-bi-pyridine, pyrazine) were synthesized via the reaction of CuI with AsPh3 and N,N'-ditopic co-ligand s L. At ambient temperature, these polymers exhibit short-lived (2.3–3.2 μs) thermally activated delayed fluorescence (TADF) with max at 530 nm (L = 4,4'-bipyridine) and 605 nm (L = pyrazine) and quantum efficiency up to 45%.
Citation:
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “1D CuI coordination polymers based on triphenylarsine and N,N'-ditopic co-ligands: synthesis, crystal structure and TADF properties”, Mendeleev Commun., 32:5 (2022), 649–651
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https://www.mathnet.ru/eng/mendc755
https://www.mathnet.ru/eng/mendc/v32/i5/p649
This publication is cited in the following 8 articles:
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Yan V. Demyanov, Zihao Ma, Zhenglin Jia, Marianna I. Rakhmanova, Gia M. Carignan, Irina Yu. Bagryanskaya, Veronika S. Sulyaeva, Anastasiya A. Globa, Valery K. Brel, Lingqiang Meng, Hong Meng, Qianqian Lin, Jing Li, Alexander V. Artemev, “Copper(I)‐Arsine Clusters with a Near‐Unity Phosphorescence Quantum Yield for X‐Ray Scintillation and LED Applications”, Advanced Optical Materials, 12:14 (2024)
Ya. V. Demyanov, I. Yu. Bagryanskaya, A. V. Artem'ev, “CuI and AgI scorpionate-like complexes based on sterically hindered tris(6-methyl-2-pyridyl)phosphine oxide”, Mendeleev Commun., 34:6 (2024), 812–814
I. D. Strelnik, I. E. Kolesnikov, A. A. Kalinichev, T. P. Gerasimova, K. D. Akhmadgaleev, I. R. Dayanova, A. A. Karasik, “Is dual emission of copper subgroup d10-metal complexes a necessary and sufficient condition for ratiometric luminescence thermometry?”, Mendeleev Commun., 34:4 (2024), 457–471
Julia A. Malakhova, Aleksey S. Berezin, Evgeni M. Glebov, Viktoriya A. Sannikova, Aleksey Yu. Vorob'ev, Natalia V. Pervukhina, Dmitrii Yu. Naumov, Dmitry S. Kolybalov, Mikhail M. Syrokvashin, Katerina A. Vinogradova, “Luminescent polymorphism of mononuclear Cu(I) complexes with pyrazolo[1,5-a][1,10]phenanthrolines”, Inorganica Chimica Acta, 555 (2023), 121604
Léo Boivin, Adrien Schlachter, Daniel Fortin, Christophe Lescop, Pierre D. Harvey, “Statistical Analysis of Copper(I) Iodide and Bis(Diphenylphosphino)alkane-Based Complexes and Coordination Polymers”, Molecules, 28:23 (2023), 7781
Kazuma Kikuchi, Hiroaki Imoto, Kensuke Naka, “Robust and highly emissive copper(i) halide 1D-coordination polymers with triphenylarsine and a series of bridging N-heteroaromatic co-ligands”, Dalton Trans., 52:32 (2023), 11168
Ya. V. Demyanov, M. I. Rakhmanova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Cu4I4-cubane cluster based on tris(p-anisyl)arsine: Synthesis, crystal structure and photophysical properties”, Mendeleev Commun., 33:4 (2023), 484–486
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