Abstract:
The flammability limits of stoichiometric mixtures (20–80% H2 + 80–20% CH4) + O2 over Rh and Pd were determined in the pressure range 0–200 Torr and the temperature range 200–500 °C. It has been shown that the dark reaction in the mixture (80% H2 + 20% C4H8)stoich + O2 leads to the formation of carbon nanotubes with a mean diameter of 10–100 nm.
Citation:
N. M. Rubtsov, V. I. Chernysh, G. I. Tsvetkov, K. Ya. Troshin, I. O. Shamshin, “The features of ignition of hydrogen–methane and hydrogen–isobutene mixtures with oxygen over Rh and Pd at low pressures”, Mendeleev Commun., 32:3 (2022), 405–407
Linking options:
https://www.mathnet.ru/eng/mendc680
https://www.mathnet.ru/eng/mendc/v32/i3/p405
This publication is cited in the following 4 articles:
N. M. Rubtsov, V. I. Chernysh, G. I. Tsvetkov, K. J. Troshin, I. O. Shamshin, “Features of ignition of mixtures of hydrogen with hydrocarbons (C2, C3 and C5) over rhodium and palladium at pressures of 1–2 atm”, Mendeleev Commun., 34:1 (2024), 137–139
K. Ya. Troshin, N. M. Rubtsov, G. I. Tsvetkov, V. I. Chernysh, I. O. Shamshin, “Features of Ignition of Mixtures of Hydrogen With Hydrocarbons (C2, C3, C5) Over Rhodium and Palladium at Pressures of 1–2 atm”, Russ. J. Phys. Chem. B, 17:4 (2023), 979
Nickolai M. Rubtsov, Kirill Ya. Troshin, Michail I. Alymov, Heat and Mass Transfer, Catalytic Ignition of Hydrogen and Hydrogen-Hydrocarbon Blends Over Noble Metals, 2023, 153
K. Ya. Troshin, N. M. Rubtsov, G. I. Tsvetkov, V. I. Chernysh, I. O. Shamshin, “Osobennosti vosplameneniya smesei vodoroda s uglevodorodami S<sub>2</sub>, S<sub>3</sub>, S<sub>5</sub> nad rodiem i palladiem pri davleniyakh 1–2 atm”, Himičeskaâ fizika, 42:8 (2023), 74
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