N. O. Yarosh, L. V. Zhilitskaya, I. V. Sterkhova, M. E. Plyaskin, B. A. Shainyan, “Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane”, Mendeleev Commun., 32:3 (2022), 379

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Mendeleev Communications, 2022, Volume 32, Issue 3, Pages 379–381
DOI: https://doi.org/10.1016/j.mencom.2022.05.029 (Mi mendc670)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane

N. O. Yarosh^a, L. V. Zhilitskaya^a, I. V. Sterkhova^a, M. E. Plyaskin^bc, B. A. Shainyan^a

^a A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation
^b L.V. Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russian Federation
^c Siberian Federal University, Krasnoyarsk, Russian Federation

Full-text PDF (292 kB) Citations (1)

DOI: https://doi.org/10.1016/j.mencom.2022.05.029

Graphic abstract: Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane

Abstract: Tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane were synthesized by the reaction of BrMgC≡CSi(CH₂Cl)Me₂ with SiCl₄/GeCl₄. Their structures were proved by IR, NMR spectroscopy and X-ray analysis, and compared to the results of MP2/6-311G(d,p) calculations.

Keywords: organosilicon compounds, organogermanium compounds, alkynes, X-ray analysis, quantum chemical calculations.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(929.9 Kb)

Citation: N. O. Yarosh, L. V. Zhilitskaya, I. V. Sterkhova, M. E. Plyaskin, B. A. Shainyan, “Synthesis and structure of tetrakis[(chloromethyl)dimethylsilylethynyl]silane and -germane”, Mendeleev Commun., 32:3 (2022), 379–381

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https://www.mathnet.ru/eng/mendc670

https://www.mathnet.ru/eng/mendc/v32/i3/p379

This publication is cited in the following 1 articles:

Krzysztof Kuciński, “Synthesis of Alkynylsilanes: A Review of the State of the Art”, Adv Synth Catal, 366:11 (2024), 2382

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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