Abstract:
New polycyclic aromatic derivatives annulated both with thiophene and with 15-crown-5 ether moieties, crown naphthothiophenes, were synthesized via the Mallory photocyclization with the use of iodine as the mild oxidizer, while two isomeric products were readily separated by column chromatography. Their complexation with Ba2+ and Mg2+ cations was examined by both optical and electrochemical methods. Spectroelectrochemical studies indicate that the obtained compounds, depending on their structure, can be chemically stable in the oxidized state
Citation:
S. D. Tokarev, A. Botezatu, A. V. Khoroshutin, Yu. V. Fedorov, O. A. Fedorova, “Optical and electrochemical properties of novel fused tricyclic thiophene–15-crown-5 systems and their complexes with Mg and Ba ions”, Mendeleev Commun., 32:3 (2022), 367–370
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https://www.mathnet.ru/eng/mendc666
https://www.mathnet.ru/eng/mendc/v32/i3/p367
This publication is cited in the following 4 articles:
Pavel A. Panchenko, Anastasija V. Efremenko, Anna S. Polyakova, Alexey V. Feofanov, Maria A. Ustimova, Yuri V. Fedorov, Olga A. Fedorova, “Application of RET Approach for Ratiometric Response Enhancement of ICT Fluorescent Hg2+ Probe based on Crown‐containing Styrylpyridinium Dye”, Chemistry — An Asian Journal, 2024
Andrey Khoroshutin, Leonid Martynov, Polina Yaltseva, Evita Kostenko, Dmitry Cheshkov, Anatoliy Botezatu, Anna Moiseeva, Yuri Fedorov, Olga Fedorova, “Congestion effect of an annulated tetracyclic thiophene-containing fragment on 18-crown-6 ether: manifestation in complex formation in solution and membrane transfer properties”, New J. Chem., 48:31 (2024), 13927
A. S. Polyakova, P. A. Panchenko, A. V. Efremenko, A. V. Feofanov, Yu. V. Fedorov, O. A. Fedorova, “A naphthalimide-based fluorescent and colorimetric probe for the detection of mercury(II) ions in aqueous solutions and in living cells”, Mendeleev Commun., 34:3 (2024), 418–420
P. A. Yaltseva, A. V. Khoroshutin, A. A. Moiseeva, S. D. Tokarev, V. M. Eliseev, A. E. Aleksandrov, A. R. Tameev, A. V. Anisimov, Yu. V. Fedorov, O. A. Fedorova, “Methoxy-substituted benzo[b]naphtho[2,1-d]thiophenes and their properties relevant for optoelectronic applications”, Mendeleev Commun., 33:5 (2023), 705–707
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