L. A. Bulygina, N. S. Khrushcheva, K. A. Lyssenko, A. S. Peregudov, “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction”, Mendeleev Commun., 32:3 (2022), 331

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Mendeleev Communications, 2022, Volume 32, Issue 3, Pages 331–333
DOI: https://doi.org/10.1016/j.mencom.2022.05.012 (Mi mendc653)

This article is cited in 5 scientific papers (total in 5 papers)

Communications

Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

L. A. Bulygina^a, N. S. Khrushcheva^a, K. A. Lyssenko^bc, A. S. Peregudov^a

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Full-text PDF (230 kB) Citations (5)

DOI: https://doi.org/10.1016/j.mencom.2022.05.012

Graphic abstract: Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction

Abstract: New bicyclic unsymmetrical CNN palladium 5,6-membered pincer complex was synthesized from 3-ferrocenylmethyl-8-dimethylamino-3-azabicyclo[3.2.1]octane by its direct cyclo-palladation with Li₂PdCl₄ or Na₂PdCl₄ and sodium acetate in MeOH. The obtained complex exhibited high catalytic activity in the Suzuki cross-coupling between aryl bromides and phenylboronic acid.

Keywords: unsymmetrical pincer complexes, palladium complexes, ferrocene, bicyclic ligand precursor, Suzuki reaction.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(291.0 Kb)

Citation: L. A. Bulygina, N. S. Khrushcheva, K. A. Lyssenko, A. S. Peregudov, “Synthesis of unsymmetrical pincer CNN palladium complex of 8-dimethylamino-3-ferrocenylmethyl-3-azabicyclo[3.2.1]octane and its catalytic activity in the Suzuki reaction”, Mendeleev Commun., 32:3 (2022), 331–333

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https://www.mathnet.ru/eng/mendc/v32/i3/p331

This publication is cited in the following 5 articles:

O. N. Gorunova, M. P. Timerkaeva, K. A. Kochetkov, V. V. Dunina, “Influence of the structure of benzylaminate C,N-palladacycles on their catalytic activity in the Suzuki—Miyaura reaction”, Russ Chem Bull, 73:3 (2024), 733
Francisco Reigosa, Paula M. Polo, M. Teresa Pereira, José M. Vila, “Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd3W2 coordinated complexes”, Dalton Trans., 53:23 (2024), 9680
A. S. Kozlov, O. I. Afanasyev, M. A. Losev, M. I. Godovikova, D. A. Chusov, “Nitrogen ligand influence on the CO-assisted ruthenium-catalyzed reductive amination”, Mendeleev Commun., 33:2 (2023), 174–176
A. F. Schmidt, A. A. Kurokhtina, E. V. Larina, N. A. Lagoda, S. A. Gurevich, D. A. Yavsin, I. N. Krotova, V. M. Zelikman, T. N. Rostovshchikova, I. G. Tarkhanova, “Advanced heterogeneous Pd catalysts for the Suzuki–Miyaura reaction with aryl bromides”, Mendeleev Commun., 33:2 (2023), 177–179
Ummuhan Solmaz, Hakan Arslan, “Spectral, crystallographic, theoretical, and catalytic activity studies of the PdII complexes in different coordination modes of benzoylthiourea ligand”, Journal of Molecular Structure, 1269 (2022), 133839

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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