Abstract:
Three-dimensional polymers are synthesized by polycondensation of triacetylarenes with the formation of 1,3,5-phentriyl and dimeric diphenylpropenone fragments. Microporous polyphenylenes with an intrinsic surface area of 650–690 m2 g–1 were obtained by additional heating at 450 °C. The values of the intrinsic surface area of polyphenylenes with rigid-chain rod-shaped inter-nodal fragments significantly exceed those of polyphenylenes with a flexible-chain inter-nodal fragments.
Citation:
A. I. Kovalev, I. A. Khotina, “Microporous polymers based on triacetylarenes”, Mendeleev Commun., 32:2 (2022), 244–246
Linking options:
https://www.mathnet.ru/eng/mendc627
https://www.mathnet.ru/eng/mendc/v32/i2/p244
This publication is cited in the following 4 articles:
Alexey I. Kovalev, Irina A. Khotina, Maria A. Kovaleva, Alexander V. Naumkin, Irina S. Ionova, Yaroslav O. Mezhuev, “Polyphenylenepyridines Based on Acetylaromatic Compounds”, J. Compos. Sci., 7:9 (2023), 359
M. A. Kovaleva, A. I. Kovalev, I. A. Khotina, “Alternative pathways of the reaction between acetophenone and triethyl orthoformate”, Russ Chem Bull, 72:5 (2023), 1186
A. S. Shabaev, Z. Kh. Kalazhokov, S. Yu. Khashirova, Kh. Kh. Kalazhokov, I. V. Dolbin, “Stability of bridging groups of polyether ether ketone during thermal destruction and exposure to ion beams”, Russ Chem Bull, 72:6 (2023), 1422
V. S. Romanova, I. A. Khotina, N. S. Kushakova, A. I. Kovalev, V. G. Kharitonova, D. V. Kupriyanova, A. V. Naumkin, “Compound based on star-shaped oligophenylene and fullerene C60”, Mendeleev Commun., 32:6 (2022), 783–785
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