Abstract:
Circumambulatory rearrangements of dithioacyloxy groups around the cyclopentadiene ring have been found to occur by a 3,3-sigmatropic shift (hetero-Cope) mechanism with energy barriers in the range of 24–30 kcal mol–1.
Document Type:
Article
Language: English
Citation:
I. E. Mikhailov, G. A. Dushenko, O. E. Kompan, Yu. T. Struchkov, A. Zschunke, C. Muegge, V. N. Drozd, V. I. Minkin, “Circumambulatory Rearrangements of Dithioacyloxy Groups around the Cyclopentadiene Ring”, Mendeleev Commun., 4:4 (1994), 120–122
Linking options:
https://www.mathnet.ru/eng/mendc5179
https://www.mathnet.ru/eng/mendc/v4/i4/p120
This publication is cited in the following 4 articles:
G. A. Dushenko, I. E. Mikhailov, O. I. Mikhailova, R. M. Minyaev, V. I. Minkin, “Mechanisms of rearrangements of substituted thiocyclopropenes”, Dokl Chem, 452:1 (2013), 220
Sergei M. Lukyanov, Alla V. Koblik, Patai's Chemistry of Functional Groups, 2009
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, R. V. Skachkov, V. I. Minkin, “Synthesis and Rearrangements of 5-(1,2,3,4,5-Pentaphenylcyclopentadienyl)-isoselenocyanate”, Mendeleev Commun., 5:5 (1995), 182–184
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Muegge, V. I. Minkin, “Fluxional Behaviour of 7-Cyclohepta-1,3,5-trienyl Ethoxydithiocarbonate”, Mendeleev Commun., 5:4 (1995), 133–134