Mendeleev Communications
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS


Mendeleev Commun.:
Year:
Volume:
Issue:
Page:
Find




Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register

Mendeleev Communications, 2023, Volume 33, Issue 5, Pages 693–695
DOI: https://doi.org/10.1016/j.mencom.2023.09.032 (Mi mendc497) 		 
This article is cited in 1 scientific paper (total in 1 paper)

Communications

Tantalum pentachloride-catalyzed reactions of alkynes with Et3Al

R. N. Kadikova, A. K. Amirova, O. S. Mozgovoj, I. R. Ramazanov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
Full-text PDF (179 kB) Citations (1)
DOI: https://doi.org/10.1016/j.mencom.2023.09.032
Abstract: Tantalum pentachloride-catalyzed reaction of 1,2-dialkyl-acetylenes with Et3Al affords regio- and stereoselectively tetraalkyl-substituted (Z,E)-hexa-1,3-dienes and (Z)-tri-substituted olefins in a ratio of 2 : 1. In cases of 1-alkynylphosphines, 1-alkynylsilanes and 2-alkynylamines, the corresponding functionalized monoolefins are formed.
Keywords: tantalum(v) pentachloride, triethylaluminum, 1-alkynylphosphines, dialkyl-substituted alkynes, dienes, ethylalumination, homocoupling.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (1.5 Mb)


Citation: R. N. Kadikova, A. K. Amirova, O. S. Mozgovoj, I. R. Ramazanov, “Tantalum pentachloride-catalyzed reactions of alkynes with Et3Al”, Mendeleev Commun., 33:5 (2023), 693–695
Linking options:
  • https://www.mathnet.ru/eng/mendc497
  • https://www.mathnet.ru/eng/mendc/v33/i5/p693
    • This publication is cited in the following 1 articles:
    1. I. R. Ramazanov, R. N. Kadikova, A. M. Gabdullin, U. M. Dzhemilev, “Catalytic carbozincation of acetylenic compounds catalyzed by transition metal complexes”, Russian Chem. Reviews, 94:3 (2025), RCR5158  mathnet  mathnet  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
    		Mendeleev Communications
    Statistics & downloads:
    Abstract page:20
    Full-text PDF :7
     
      Contact us:
    		  Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2025