Abstract:MNDO/PM3 calculations have proved the possibility of the existence in mBr2nAlBr3 systems of highly electrophilic complexes with bidentate coordination of AlBr4-anions with a positively charged (up to + 1.45 a.u.) Br atom.
Document Type:
Article
Language: English
Citation:
A. L. Chistyakov, I. V. Stankevich, I. S. Akhrem, N. P. Gambaryan, M. E. Vol'pin, “Superelectrophiles generated in mBr2nAlBr3 systems”, Mendeleev Commun., 6:5 (1996), 175–178
Linking options:
https://www.mathnet.ru/eng/mendc4965
https://www.mathnet.ru/eng/mendc/v6/i5/p175
This publication is cited in the following 5 articles:
Irena Akhrem, Alexander Orlinkov, “Polyhalomethanes Combined with Lewis Acids in Alkane Chemistry”, Chem. Rev., 107:5 (2007), 2037
A. L. Chistyakov, I. V. Stankevich, N. P. Gambaryan, I. S. Akhrem, “Mechanism of methane activation by electrophiles generated in the AlBr5 system: An MNDO/PM3 study of the potential energy surface of the [AlBr5+CH4] system”, Russ Chem Bull, 49:5 (2000), 799
A. L. Chistyakov, I. V. Stankevich, N. P. Gambaryan, I. S. Akhrem, “MNDO/PM3 study of the mechanism of a model reaction between methane and Br+ cation”, Russ Chem Bull, 47:9 (1998), 1666
I. S. Akhrem, A. V. Orlinkov, “Novel superelectrophilic complexes for low-temperature alkane and cycloalkane transformations”, Russ Chem Bull, 47:5 (1998), 740
A. L. CHISTYAKOV, I. V. STANKEVICH, I. S. AKHREM, N. P. GAMBARYAN, M. E. VOL'PIN, “ChemInform Abstract: Superelectrophiles Generated in mBr2×nAlBr3 Systems.”, ChemInform, 28:5 (1997)
Contact us: