Abstract:
The interaction of octahydroxytetraheptyl[l4]methacyclophane 1 with bis(N,N-diethylamido)menthylphosphite under mild conditions with a different ratio of initial reagents (1 : 8, 1 : 4, 1 : 2) yields either the completely phosphorylated optically active product (for ratio 1:8), or the product of partial phosphorylation (for ratio 1:4); the corresponding phosphates and thiophosphates also were obtained. An optically inactive product with two tetraresorcinol fragments united by phosphite bridges is formed under more severe reaction conditions and with a ratio of reagents 1 : 2.
Document Type:
Article
Language: English
Citation:
E. Kh. Kazakova, A. I. Konovalov, L. V. Snegur, V. N. Babin, Yu. S. Nekrasov, M. A. Pudovik, “Interaction of resorcinol–octanal cyclotetramer with bis(N,N-diethylamido)menthylphosphite”, Mendeleev Commun., 6:4 (1996), 157–159
Linking options:
https://www.mathnet.ru/eng/mendc4959
https://www.mathnet.ru/eng/mendc/v6/i4/p157
This publication is cited in the following 7 articles:
I. R. Knyazeva, A. R. Burilov, M. A. Pudovik, W. D. Habicher, “Phosphorus-containing macrocyclic compounds: synthesis and properties”, Russian Chem. Reviews, 82:2 (2013), 150–186
V. I. Maslennikova, R. V. Merkulov, L. K. Vasyanina, I. Bauer, D. Weber, G. Theumer, W. D. Habicher, E. E. Nifantyev, “Approaches to the Synthesis of Conjugates of Phosphocavitands and Natural Compounds”, Phosphorus, Sulfur, and Silicon and the Related Elements, 178:7 (2003), 1489
Edward E. Nifantiev, Mikhail K. Grachev, Sergei Yu. Burmistrov, “Amides of Trivalent Phosphorus Acids as Phosphorylating Reagents for Proton-Donating Nucleophiles”, Chem. Rev., 100:10 (2000), 3755
Myroslav Vysotsky, Christian Schmidt, Volker Böhmer, Advances in Supramolecular Chemistry, 7, 2000, 139
I. S. Antipin, E. Kh. Kazakova, W. D. Habicher, A. I. Konovalov, “Phosphorus-containing calixarenes”, Russian Chem. Reviews, 67:11 (1998), 905–922
Alexander I. Konovalov, Vladimir S. Reznik, Michael A. Pudovik, Ella Kh. Kazakova, Alexander R. Burilov, Irina L. Nikolaeva, Nelly A. Makarova, Guzel R. Davlet-schina, Ludmila V. Ermolaeva, Rustem D. Galimov, Asija R. Mustafina, “SYNTHESIS OF NEW PHOSPHORUSCONTAINING THREE-DIMENSIONAL STRUCTURES ON THE BASIS OF CALIX[4] RESORCINARENES”, Phosphorus, Sulfur, and Silicon and the Related Elements, 123:1 (1997), 277
E. KH. KAZAKOVA, N. A. MAKAROVA, V. V. ZOTKINA, A. R. BURILOV, M. A. PUDOVIK, A. I. KONOVALOV, “ChemInform Abstract: Interaction of Resorcinol‐Octanal Cyclotetramer with Bis(N,N‐ diethylamido)menthylphosphite.”, ChemInform, 27:46 (1996)
Contact us: