E. I. Troyanskii, M. S. Pogosyan, N. M. Samoshina, G. I. Nikishin, V. V. Samoshin, L. K. Shpigun, N. E. Kopytova, P. M. Kamilova, “Crown thioethers and 1,4-dithiacyclanes immobilized on silica carrier: preparation and studies of complexation affinity towards metal ions”, Mendeleev Commun., 6:1 (1996), 9

Abstract: Crown thioethers and their non-macrocyclic analogues have been immobilized on a silica matrix coated with (ω-(triethoxysiryl)-undecanoic acid. Thiacrown modified silica carriers were found to be highly suitable as complex-forming adsorbents for silver(I) and gold(III) ions under dynamic conditions, and application of their complexation affinity for preparation of solid-state electrochemical sensors based on composite carbon-paste electrodes has been demonstrated.

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