Abstract:
Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid 10−14 have been synthesized for the first time and characterized by spectroscopic methods; nucleophilic reactions of dimethyl 1-fluoroaziridine-2,2-dicarboxylate, such as transesterification and amidation, occur predominantly at the carboxy group trans-oriented with respect to the N-substituent.
Document Type:
Article
Language: English
Citation:
R. G. Kostyanovsky, I. I. Chervin, G. K. Kadorkina, K. N. Makarov, L. T. Lantzeva, V. V. Rozhkov, A. V. Prosyanik, “Derivatives of 1-fluoroaziridine-2,2-dicarboxylic acid”, Mendeleev Commun., 7:2 (1997), 54–55
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https://www.mathnet.ru/eng/mendc4779
https://www.mathnet.ru/eng/mendc/v7/i2/p54
This publication is cited in the following 4 articles:
Fabio Prati, Arrigo Forni, Irene Moretti, Giovanni Torre, Vladimir V. Rozhkov, Kirill N. Makarov, Ivan I. Chervin, Remir G. Kostyanovsky, “Synthesis and stereodirected N-halogenation of trans-3-trifluoromethyl-2-methoxycarbonylaziridine”, Journal of Fluorine Chemistry, 89:2 (1998), 177
V. V. Rozhkov, K. N. Makarov, R. G. Kostyanovsky, “N-Fluorination of aziridinecarboxylates via fluorolysis of their N-aminomethyl derivatives”, Mendeleev Commun., 8:2 (1998), 66–67
R. G. KOSTYANOVSKY, I. I. CHERVIN, G. K. KADORKINA, K. N. MAKAROV, L. T. LANTZEVA, V. V. ROZHKOV, A. V. PROSYANIK, “ChemInform Abstract: Derivatives of 1‐Fluoroaziridine‐2,2‐dicarboxylic Acid.”, ChemInform, 28:38 (1997)
V. V. Rozhkov, K. N. Makarov, S. N. Osipov, I. I. Chervin, A. V. Ignatenko, R. G. Kostyanovsky, “Methyl 2-trifluoromethylaziridine-2-carboxylate: stereodirected N-halogenation from the sterically more hindered side”, Mendeleev Commun., 7:6 (1997), 229–230
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