N. I. Osipova, A. V. Plutalova, R. V. Toms, N. I. Prokopov, E. V. Chernikova, “Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole”, Mendeleev Commun., 33:4 (2023), 568

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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 568–571
DOI: https://doi.org/10.1016/j.mencom.2023.06.041 (Mi mendc462)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole

N. I. Osipova^a, A. V. Plutalova^a, R. V. Toms^b, N. I. Prokopov^b, E. V. Chernikova^a

^a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation

Full-text PDF (850 kB) Citations (1)

DOI: https://doi.org/10.1016/j.mencom.2023.06.041

Graphic abstract: Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole

Abstract: The copolymers of acrylonitrile and 1-vinylimidazole with a narrow molecular weight distribution (MWD) were synthesized for the first time by the reversible addition–fragmentation chain transfer (RAFT) polymerization in a DMSO solution in the presence of acetic acid. Their thermal behavior difference upon heating in argon and in air along with ability to melt make them promising precursors for carbon fiber production.

Keywords: reversible addition–fragmentation chain transfer polymerization, acrylonitrile copolymers, 1-vinylimidazole, cyclization, thermo-oxidative stabilization, melt spinning.

Document Type: Article

Language: English

Citation: N. I. Osipova, A. V. Plutalova, R. V. Toms, N. I. Prokopov, E. V. Chernikova, “Synthesis and thermal behavior of RAFT-based copolymers of acrylonitrile and 1-vinylimidazole”, Mendeleev Commun., 33:4 (2023), 568–571

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https://www.mathnet.ru/eng/mendc462

https://www.mathnet.ru/eng/mendc/v33/i4/p568

This publication is cited in the following 1 articles:

A. E. Tarasov, A. A. Grishchuk, Yu. V. Podval'naya, E. R. Badamshina, M. V. Mironova, M. S. Kuzin, I. Yu. Skvortsov, V. G. Kulichikhin, “Molecular weight and spinnability of polyacrylonitrile: control with water and 1,8-diazabicyclo[5.4.0]undec-7-ene during anionic polymerization in dimethyl sulfoxide”, Mendeleev Commun., 34:5 (2024), 740–742

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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