Abstract:
In 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isothiocyanate and isoselenocyanate, migration of isothiocyanate and isoselenocyanate groups along the perimeter of the seven-membered ring occurs via an intramolecular dissociation–recombination mechanism with high free energy barriers (ΔG298≠) of 24.3 and 22.4 kcal mol–1, respectively.
Document Type:
Article
Language: English
Citation:
G. A. Dushenko, I. E. Mikhailov, A. Zschunke, G. Reck, B. Schulz, V. I. Minkin, “Structure and rearrangements of 7-(1,2,3,4,5,6,7-heptaphenylcycloheptatrienyl) isocyanate, isothiocyanate and isoselenocyanate”, Mendeleev Commun., 9:6 (1999), 222–225
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https://www.mathnet.ru/eng/mendc4607
https://www.mathnet.ru/eng/mendc/v9/i6/p222
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