Abstract:
The σ,π-mixing responsible for the Z,Z configuration of the title compounds is indifferent to both withdrawing (NO2) and releasing (OMe) π-electron character of ortho-substituents, and the arrangement of aromatic rings in the Z,E configuration orthogonally to the NSN plane is a universal way to overcome steric hindrances due to bulky (But, Br) ortho-substituents.
Document Type:
Article
Language: English
Citation:
I. Yu. Bagryanskaya, Yu. V. Gatilov, A. V. Zibarev, “Configurations of 1,3-bis(aryl)-1,3-diaza-2-thiaallenes in the crystal state”, Mendeleev Commun., 9:4 (1999), 157–158
Linking options:
https://www.mathnet.ru/eng/mendc4572
https://www.mathnet.ru/eng/mendc/v9/i4/p157
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Rebecca L. Melen, Jeremy M. Rawson, Dana J. Eisler, “Structural studies of copper(II) complexes derived from di-2-pyridyl-ketone, (py)2CO”, Polyhedron, 47:1 (2012), 16
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Frank Blockhuys, Nina P. Gritsan, Alexander Yu. Makarov, Karla Tersago, Andrey V. Zibarev, “A Brave New World: The Heteroatom Chemistry of 1,3,2,4‐Benzodithiadiazines and Related Compounds”, Eur J Inorg Chem, 2008:5 (2008), 655
Karla Tersago, Marcos Mandado, Christian Van Alsenoy, Irina Yu. Bagryanskaya, Mikhail K. Kovalev, Alexander Yu. Makarov, Yuri V. Gatilov, Makhmut M. Shakirov, Andrey V. Zibarev, Frank Blockhuys, “Does a Stabilising Interaction Favouring theZ,ZConfiguration of S‐NSN‐S Systems Exist?”, Chemistry A European J, 11:15 (2005), 4544
Tiina Maaninen, Heikki M. Tuononen, Katja Kosunen, Raija Oilunkaniemi, Johanna Hiitola, Risto Laitinen, Tristram Chivers, “Formation, Structural Characterization, and Calculated NMR Chemical Shifts of Selenium‐Nitrogen Compounds from SeCl4 and ArNHLi (Ar = supermesityl, mesityl)”, Zeitschrift anorg allge chemie, 630:12 (2004), 1947
I. Yu. Bagryanskaya, Yu. V. Gatilov, M. M. Shakirov, A. V. Zibarev, “The first stable R–N=S=N–H sulfur diimide”, Mendeleev Commun., 12:5 (2002), 167–168
Enno Lork, Rüdiger Mews, Makhmut M. Shakirov, Paul G. Watson, Andrey V. Zibarev, “Reactions of Arylthiazylamides with Internal and External Fluoro Electrophiles - Formation of Products with Unusual Structures”, Eur. J. Inorg. Chem., 2001:8 (2001), 2123
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