Abstract:
(R,R)-1,2-Di-(2,4,6-trimethylbenzylamino)-1,2-diphenylethane (the Corey chiral controller) was found to be an effective chiral NMR shift reagent for the determination of the enantiomer ratio in chiral carboxylic and sulfonic acids and cyclic β-diketones.
Document Type:
Article
Language: English
Citation:
M. A. Lapitskaya, G. V. Zatonsky, K. K. Pivnitsky, “Enantiomeric NMR analysis of organic acids with the Corey chiral controller”, Mendeleev Commun., 9:4 (1999), 149–151
Linking options:
https://www.mathnet.ru/eng/mendc4569
https://www.mathnet.ru/eng/mendc/v9/i4/p149
This publication is cited in the following 4 articles:
Marcio S. Silva, Daniel Pietrobom, “Chiral discrimination of β-telluride carboxylic acids by NMR spectroscopy”, New J. Chem., 39:11 (2015), 8240
Andrey E. Sheshenev, Ekaterina V. Boltukhina, Anastasiya A. Grishina, Ivana Cisařova, Ilya M. Lyapkalo, King Kuok (Mimi) Hii, “New Chiral Zwitterionic Phosphorus Heterocycles: Synthesis, Structure, Properties and Application as Chiral Solvating Agents”, Chemistry A European J, 19:25 (2013), 8136
Thomas J. Wenzel, James D. Wilcox, “Chiral reagents for the determination of enantiomeric excess and absolute configuration using NMR spectroscopy”, Chirality, 15:3 (2003), 256
Margarita A. Lapitskaya, Georgy V. Zatonsky, Kasimir K. Pivnitsky, “ChemInform Abstract: Enantiomeric NMR Analysis of Organic Acids with the Corey Chiral Controller.”, ChemInform, 30:44 (1999)