Abstract:
Novel square-planar Pt-based heterometallic complexes with ferrocenecarboxylic acid were prepared in two steps from (tetrapyridine)platinum diacetate [PtPy4](OAc)2. The crystal structure of [PtPy4](FcCOO)2 and [PtPy2(FcCOO)2] was established by single crystal X-ray diffraction. Subsequent thermal transformation of a trinuclear compound [PtPy2(FcCOO)2] to a bimetallic Pt–Fe phase was studied by XAFS techniques.
Citation:
I. A. Yakushev, N. K. Ogarkova, E. V. Khramov, N. S. Smirnova, M. Yu. Nesterenko, N. V. Cherkashina, A. G. Medvedev, M. V. Panina, M. N. Vargaftik, A. S. Popova, “Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]”, Mendeleev Commun., 33:4 (2023), 487–490
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https://www.mathnet.ru/eng/mendc436
https://www.mathnet.ru/eng/mendc/v33/i4/p487
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