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Mendeleev Communications, 2023, Volume 33, Issue 4, Pages 487–490
DOI: https://doi.org/10.1016/j.mencom.2023.06.015
(Mi mendc436)
 

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]

I. A. Yakusheva, N. K. Ogarkovaab, E. V. Khramovac, N. S. Smirnovaad, M. Yu. Nesterenkoa, N. V. Cherkashinaa, A. G. Medvedeva, M. V. Paninaa, M. N. Vargaftika, A. S. Popovaab

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
c National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
d N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (586 kB) Citations (1)
Abstract: Novel square-planar Pt-based heterometallic complexes with ferrocenecarboxylic acid were prepared in two steps from (tetrapyridine)platinum diacetate [PtPy4](OAc)2. The crystal structure of [PtPy4](FcCOO)2 and [PtPy2(FcCOO)2] was established by single crystal X-ray diffraction. Subsequent thermal transformation of a trinuclear compound [PtPy2(FcCOO)2] to a bimetallic Pt–Fe phase was studied by XAFS techniques.
Keywords: platinum complexes, ferrocenecarboxylic acid, thermolysis, X-ray absorption spectroscopy, platinum–iron intermetallic compounds.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (917.5 Kb)


Citation: I. A. Yakushev, N. K. Ogarkova, E. V. Khramov, N. S. Smirnova, M. Yu. Nesterenko, N. V. Cherkashina, A. G. Medvedev, M. V. Panina, M. N. Vargaftik, A. S. Popova, “Synthesis, crystal structure, and thermal behavior of Pt-based heterometallics [PtPy4](FcCOO)2 and trans-[PtPy2(FcCOO)2]”, Mendeleev Commun., 33:4 (2023), 487–490
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  • https://www.mathnet.ru/eng/mendc/v33/i4/p487
  • This publication is cited in the following 1 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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