Abstract:
The title reaction was performed with 1,3,5-trinitrobenzene and 1-X-3,5-dinitrobenzenes (X = CF3, ArO) in the presence of K2CO3 in N-methylpyrrolidone or DMF solutions to form O-3,5-dinitrophenyl oximes or O-3-X-5-nitrophenyl oximes, respectively.
Document Type:
Article
Language: English
Citation:
S. A. Shevelev, I. A. Vatsadze, M. D. Dutov, “Substitution for a nitro group in 1,3,5-trinitrobenzene and meta-substituted 1,3-dinitrobenzenes under the action of oximes”, Mendeleev Commun., 12:5 (2002), 196–198
Linking options:
https://www.mathnet.ru/eng/mendc4158
https://www.mathnet.ru/eng/mendc/v12/i5/p196
This publication is cited in the following 9 articles:
M. D. Dutov, V. V. Kachala, B. I. Ugrak, V. A. Korolev, S. V. Popkov, D. R. Aleksanyan, O. N. Rusina, K. G. Aleksanyan, V. N. Koshelev, “Synthesis and fungicidal activity of new 4-hydroxy-6-trifluoromethyl-2-phenylindoles”, Mendeleev Commun., 28:4 (2018), 437–438
M. D. Dutov, S. A. Shevelev, V. N. Koshelev, D. R. Aleksanyan, O. V. Serushkina, O. D. Neverova, E. V. Kolvina, E. S. Bobrov, “Dual reactivity of 1-chloro- and 1-bromo-3,5-dinitrobenzenes in aromatic nucleophilic substitution”, Mendeleev Commun., 27:2 (2017), 160–162
Modern Nucleophilic Aromatic Substitution, 2013, 205
Handbook of Acid-Base Indicators, 2007, 115
S. S. Vorob'ev, M. D. Dutov, I. A. Vatsadze, E. P. Petrosyan, V. V. Kachala, Yu. A. Strelenko, S. A. Shevelev, “Intramolecular cyclization of O-(3,5-dinitrophenyl) and O-(3-amino-5-nitrophenyl) ketoximes, products of transformations of 1,3,5-trinitrobenzene. The synthesis of nitrobenzo[b]furans and 4-hydroxynitroindoles”, Russ Chem Bull, 56:5 (2007), 1020
M. D. Dutov, S. S. Vorob'ev, O. V. Serushkina, S. A. Shevelev, B. I. Ugrak, V. V. Kachala, “Reactions of ortho-aminophenols and ortho-aminothiophenols with 1,3,5-trinitrobenzene”, Mendeleev Commun., 16:4 (2006), 230–232
I. A. Khalfina, V. M. Vlasov, “Mechanism of Replacement of the Nitro Group and Fluorine Atom in meta-Substituted Nitrobenzenes by Phenols in the Presence of Potassium Carbonate”, Russ J Org Chem, 41:7 (2005), 978
M. D. Dutov, I. A. Vatsadze, S. S. Vorob'ev, S. A. Shevelev, “Synthesis of 4,6-dinitrobenzo[b]furans from 1,3,5-trinitrobenzene”, Mendeleev Commun., 15:5 (2005), 202–204
Svyatoslav A. Shevelev, Irina A. Vatsadze, Mikhail D. Dutov, “Substitution for a Nitro Group in 1,3,5‐Trinitrobenzene and meta‐Substituted 1,3‐Dinitrobenzenes under the Action of Oximes.”, ChemInform, 34:13 (2003)
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