Abstract:
Captodative formyl(amino)alkenes react with N,O-binucleophiles in a cascade fashion to result mainly in dioximes (in the case of hydroxylamine) or oxazoline derivatives (in the case of 2-amino-2-methylpropanole).
Document Type:
Article
Language: English
Citation:
A. Yu. Rulev, L. I. Larina, Yu. A. Chuvashev, V. V. Novokshonov, “Cascade reactions of captodative formyl(amino)alkenes with N,O-binucleophiles”, Mendeleev Commun., 15:3 (2005), 128–130
Linking options:
https://www.mathnet.ru/eng/mendc3710
https://www.mathnet.ru/eng/mendc/v15/i3/p128
This publication is cited in the following 5 articles:
A. Yu. Rulev, “Assembly of nitrogen-containing heterocycles initiated by the aza-Michael reaction”, Russ Chem Bull, 65:7 (2016), 1687
Valentine G. Nenajdenko, Vasiliy M. Muzalevskiy, Aleksey V. Shastin, Elizabeth S. Balenkova, Evgeniy V. Kondrashov, Igor A. Ushakov, Alexander Yu. Rulev, “Fragmentation of Trifluoromethylated Alkenes and Acetylenes by N,N-Binucleophiles. Synthesis of Imidazolines or Imidazolidines (Oxazolidines) Controlled by Substituent”, J. Org. Chem., 75:16 (2010), 5679
V. R. Akhmetova, G. R. Nadyrgulova, Z. T. Niatshina, U. M. Dzhemilev, “Cyclothiomethylation of primary amines with formaldehyde and hydrogen sulfide to nitrogen- and sulfur-containing heterocycles (review)”, Chem Heterocycl Comp, 45:10 (2009), 1155
V. R. Akhmetova, G. R. Nadyrgulova, T. V. Tyumkina, Z. A. Starikova, M. Yu. Antipin, R. V. Kunakova, U. M. Dzhemilev, “Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide”, Russ J Org Chem, 43:6 (2007), 918
Alexander Yu. Rulev, Lyudmila I. Larina, Yuri A. Chuvashev, Vladimir V. Novokshonov, “Cascade Reactions of Captodative Formyl(amino)alkenes with N,O‐Binucleophiles.”, ChemInform, 36:38 (2005)
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