Abstract:
The interaction of ent-16α-hydroxybeyeran-19-oate with PCl3 yielded methyl ent-16α-dichlorophosphitobeyeran-19-oate, whose hydrolysis resulted in methyl ent-16α-phosphitobeyeran-19-oate, a promising reagent for stereoselective synthesis and analysis.
Document Type:
Article
Language: English
Citation:
V. L. Mamedova, K. A. Nikitina, V. E. Kataev, V. A. Alfonsov, “Methyl ent-16α-dichlorophosphitobeyeran-19-oate as the first example of phosphorylated diterpenoid derivatives of the beyerane series”, Mendeleev Commun., 15:3 (2005), 98–99
Linking options:
https://www.mathnet.ru/eng/mendc3695
https://www.mathnet.ru/eng/mendc/v15/i3/p98
This publication is cited in the following 7 articles:
I. Yu. Strobykina, A. V. Nemtarev, B. F. Garifullin, A. D. Voloshina, A. S. Sapunova, V. E. Kataev, “Synthesis and Biological Activity of Alkane-1,1-diylbis(phosphonates) of Diterpenoid Isosteviol”, Russ J Org Chem, 55:1 (2019), 17
O. N. Kataeva, V. L. Mamedova, K. A. Nikitina, K. E. Metlushka, K. A. Ivshin, Yu. V. Krupskaya, V. E. Kataev, O. G. Sinyashin, V. A. Alfonsov, “First coordination polymer based on diterpenoids. Synthesis, structure, and magnetic properties”, Russ Chem Bull, 66:2 (2017), 362
V. L. Mamedova, D. R. Sharafutdinova, K. A. Nikitina, T. P. Gerasimova, O. B. Bazanova, V. A. Al'fonsov, “Metal derivatives of diterpenoid isosteviol”, Russ J Gen Chem, 84:4 (2014), 700
V. L. Mamedova, K. A. Nikitina, V. A. Alfonsov, “New hydrophosphoryl compounds derived from ent-16-oxobeyeran-19-oic acid”, Russ Chem Bull, 61:8 (2012), 1622
E. Kataev, R. N. Khaybullin, R. R. Sharipova, I. Yu. Strobykina, “Ent-kaurane diterpenoids and glycosides: Isolation, properties, and chemical transformations”, Ref. J. Chem., 1:2 (2011), 93
V. L. Mamedova, K. A. Nikitina, V. A. Al′fonsov, “Isosteviol acylphosphonates”, Russ Chem Bull, 58:1 (2009), 244
Vera L. Mamedova, Kristina A. Nikitina, Vakhid A. Mamedov, Vladimir E. Kataev, Vladimir A. Alfonsov, “Methyl ent‐16α‐Dichlorophosphitobeyeran‐19‐oate as the First Example of Phosphorylated Diterpenoid Derivatives of the Beyerane Series.”, ChemInform, 36:39 (2005)
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