Abstract:
The acid-catalysed protolysis of intermediates, formed either during one-electron reduction of substituted arylmercury salt (C6F5HgBr) or by the adsorption of bis(arylalkynyl)mercury compound [(PhC≡C)2Hg] on a Hg electrode has been found in lowacidic media (3 < pH < 6), whereas it was not observed in alkylmercury salt (PrnHgOAc).
Document Type:
Article
Language: English
Citation:
V. A. Kurmaz, A. B. Ershler, “Acid-catalysed degradation of the organomercury intermediates of pentafluorophenylmercury bromide reduction near a mercury electrode”, Mendeleev Commun., 16:4 (2006), 234–237
Linking options:
https://www.mathnet.ru/eng/mendc3602
https://www.mathnet.ru/eng/mendc/v16/i4/p234
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V. A. Kurmaz, A. S. Kotkin, G. V. Simbirtseva, “Investigation of electrochemical behavior of secondary products of capture of OH radicals by dimethyl sulfoxide molecules using laser photoemission”, Moscow Univ. Chem. Bull., 68:6 (2013), 273
Vladimir A. Kurmaz, Alexander S. Kotkin, Galina V. Simbirtseva, “Laser photoemission generation and electrochemical study of methyl radicals as secondary products of OH radicals capture by dimethyl sulfoxide molecules”, J Solid State Electrochem, 15:10 (2011), 2119
Pavlo V. Solntsev, Wil R. Goetsch, Victor N. Nemykin, “Formation of an Unexpected Organometallic Mercury Compound in a Palladium-Catalyzed Reaction”, Organometallics, 30:24 (2011), 6636
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