Abstract:
Under the methanolysis of N-methoxy-N-(1-pyridinium)amines salts 1a–c, nucleophilic substitution occurs at the nitrogen atom to form N,N-dimethoxyamines 2a,b; the crystal structure of precursor 1c has been studied.
Document Type:
Article
Language: English
Citation:
V. G. Shtamburg, A. V. Tsygankov, E. A. Klots, I. V. Fedyanin, K. A. Lyssenko, R. G. Kostyanovsky, “N,N-Dimethoxy-N-tert-alkylamines: new synthesis methods and the crystal structure of the precursor”, Mendeleev Commun., 16:2 (2006), 84–85
Linking options:
https://www.mathnet.ru/eng/mendc3530
https://www.mathnet.ru/eng/mendc/v16/i2/p84
This publication is cited in the following 7 articles:
V. G. Shtamburg, S. V. Shishkina, V. V. Shtamburg, A. V. Mazepa, G. K. Kadorkina, R. G. Kostyanovsky, “1-Alkoxyamino-4-dimethylaminopyridinium salts: synthesis and structure†”, Mendeleev Commun., 26:2 (2016), 169–171
V. G. Shtamburg, O. V. Shishkin, R. I. Zubatyuk, V. V. Shtamburg, A. V. Tsygankov, A. V. Mazepa, G. K. Kadorkina, R. G. Kostyanovsky, “Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N',N',N'-trialkylhydrazinium salts”, Mendeleev Commun., 23:5 (2013), 289–291
V. G. Shtamburg, E. A. Klots, M. V. Gerasimenko, O. V. Shishkin, R. I. Zubatyuk, R. G. Kostyanovsky, “N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure”, Mendeleev Commun., 21:6 (2011), 349–350
Oleg V. Shishkin, Vasiliy G. Shtamburg, Roman I. Zubatyuk, Dmitriy A. Olefir, Alexander V. Tsygankov, Alexander V. Prosyanik, Alexander V. Mazepa, Remir G. Kostyanovsky, “Chiral ureas with two electronegative substituents at 1‐N: An unusual case of coexisting pyramidal and almost planar 1‐N atoms in the same crystal”, Chirality, 21:7 (2009), 642
Vasiliy G. Shtamburg, Alexander V. Tsygankov, Evgeny A. Klots, Ivan V. Fedyanin, Konstantin A. Lyssenko, Remir G. Kostyanovsky, “N,N‐Dimethoxy‐N‐tert‐alkylamines (III): New Synthesis Method and the Crystal Structure of the Precursor (Ib).”, ChemInform, 37:35 (2006)
D. A. Lenev, K. A. Lyssenko, R. G. Kostyanovsky, “Sterically hindered fluorinated and brominated Tröger bases: synthesis and X-ray diffraction analysis”, Mendeleev Commun., 16:3 (2006), 138–139
O. V. Shishkin, R. I. Zubatyuk, V. G. Shtamburg, A. V. Tsygankov, E. A. Klots, A. V. Mazepa, R. G. Kostyanovsky, “Pyramidal amide nitrogen in N-acyloxy-N-alkoxyureas and N-acyloxy-N-alkoxycarbamates”, Mendeleev Commun., 16:4 (2006), 222–223
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