Abstract:
The reactions of boron trifluoride with triallyl- and allyldialkylboranes represent a convenient non-catalytic approach to allyl(difluoro)boranes. The rupture of 1-boraadamantane core with BF3 leads to 3-fluoro-7-difluoroborylmethyl-3-borabicyclo-[3.3.1]nonane derivatives.
Document Type:
Article
Language: English
Citation:
S. Yu. Erdyakov, A. V. Ignatenko, M. E. Gurskii, Yu. N. Bubnov, “Reactions of boron trifluoride with allylic boranes and 1-boraadamantane”, Mendeleev Commun., 17:5 (2007), 271–273
Linking options:
https://www.mathnet.ru/eng/mendc3454
https://www.mathnet.ru/eng/mendc/v17/i5/p271
This publication is cited in the following 2 articles:
Alexandre S. Dumon, Henry S. Rzepa, Carla Alamillo-Ferrer, Jordi Bures, Richard Procter, Tom D. Sheppard, Andrew Whiting, “A computational tool to accurately and quickly predict19F NMR chemical shifts of molecules with fluorine–carbon and fluorine–boron bonds”, Phys. Chem. Chem. Phys., 24:34 (2022), 20409
Yury V. Vishnevskiy, Maxim A. Abaev, Anatolii N. Rykov, Mikhail E. Gurskii, Pavel A. Belyakov, Sergey Yu. Erdyakov, Yuri N. Bubnov, Norbert W. Mitzel, “Structure and Bonding Nature of the Strained Lewis Acid 3‐Methyl‐1‐boraadamantane: A Case Study Employing a New Data‐Analysis Procedure in Gas Electron Diffraction”, Chemistry A European J, 18:34 (2012), 10585
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