S. A. Runikhina, A. A. Tsygankov, O. I. Afanasyev, D. A. Chusov, “Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis”, Mendeleev Commun., 33:1 (2023), 17

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Mendeleev Communications, 2023, Volume 33, Issue 1, Pages 17–20
DOI: https://doi.org/10.1016/j.mencom.2023.01.005 (Mi mendc294)

This article is cited in 2 scientific papers (total in 2 papers)

Communications

Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis

S. A. Runikhina^a, A. A. Tsygankov^a, O. I. Afanasyev^a, D. A. Chusov^ab

^a A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Full-text PDF (186 kB) Citations (2)

DOI: https://doi.org/10.1016/j.mencom.2023.01.005

Graphic abstract: Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis

Abstract: Fluoride additive to [(p-cymene)RuCl₂]₂, a readily available ruthenium catalyst, allows one to achieve milder conditions for the reductive alkylation of aldehydes with ketones using carbon monoxide as a reducing agent. The procedure is suitable for the broad substrate scope, and a probable explanation for the fluoride role was provided.

Keywords: carbon monoxide, fluoride activation, reductive addition, ruthenium, aldol reaction, aldehydes, ketones.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.6 Mb)

Citation: S. A. Runikhina, A. A. Tsygankov, O. I. Afanasyev, D. A. Chusov, “Reductive α-alkylation of ketones with aldehydes at atmospheric pressure of carbon monoxide: the effect of fluoride activation in ruthenium catalysis”, Mendeleev Commun., 33:1 (2023), 17–20

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https://www.mathnet.ru/eng/mendc294

https://www.mathnet.ru/eng/mendc/v33/i1/p17

This publication is cited in the following 2 articles:

Aleksei A. Tsygankov, Andrey S. Kozlov, Saihu Liao, Denis Chusov, “Application of transition metal fluorides in catalysis”, Coordination Chemistry Reviews, 519 (2024), 216114
I. V. Smirnov, O. I. Afanasyev, K. O. Biriukov, M. I. Godovikova, D. A. Chusov, “Mn-catalyzed syngas-assisted reductive Knoevenagel condensation”, Mendeleev Commun., 34:6 (2024), 831–833

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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