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This article is cited in 13 scientific papers (total in 13 papers)
The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide
V. G. Shtamburgab, A. V. Tsygankovc, O. V. Shishkind, R. I. Zubatyukd, B. V. Uspenskyb, V. V. Shtamburgb, A. V. Mazepae, R. G. Kostyanovskyf a Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
b Department of Chemistry, National Technical University 'Kharkov Polytechnic Institute', Kharkov, Ukraine
c State Flight Academy of Ukraine, Kirovograd, Ukraine
d STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
e A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
f N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract:
The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N’-bis(4-nitrobenzoyl)-N,N’-dimethoxyhydrazine.
Citation:
V. G. Shtamburg, A. V. Tsygankov, O. V. Shishkin, R. I. Zubatyuk, B. V. Uspensky, V. V. Shtamburg, A. V. Mazepa, R. G. Kostyanovsky, “The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide”, Mendeleev Commun., 22:3 (2012), 164–166
Linking options:
https://www.mathnet.ru/eng/mendc2778 https://www.mathnet.ru/eng/mendc/v22/i3/p164
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