Abstract:
As found experimentally (gas-phase electron diffraction) and theoretically, the equilibrium conformers of N-azidomethyl-N,N-dimethylamine are stabilized by anomeric effects.
Keywords:
azidomethyldimetylamine, gas-phase electron diffraction, azides, anomeric effect.
Document Type:
Article
Language: English
Citation:
E. P. Altova, O. G. Nabiev, N. M. Karasev, R. G. Kostyanovsky, L. S. Khaikin, I. F. Shishkov, “Molecular Structure of N-azidomethyl-N,N-dimethylamine According to Gas-phase Electron Diffraction Data and Quantum-chemical Calculations”, Mendeleev Commun., 23:3 (2013), 166–167
Linking options:
https://www.mathnet.ru/eng/mendc2650
https://www.mathnet.ru/eng/mendc/v23/i3/p166
This publication is cited in the following 2 articles:
Natalja Vogt, Jürgen Vogt, Structure Data of Free Polyatomic Molecules, 2019, 309
Klaus Banert, Tom Pester, “Too Short-Lived or Not Existing Species: N-Azidoamines Reinvestigated”, J. Org. Chem., 84:7 (2019), 4033