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Mendeleev Communications, 2024, Volume 34, Issue 6, Pages 808–811
DOI: https://doi.org/10.1016/j.mencom.2024.10.013
(Mi mendc258)
 

This article is cited in 1 scientific paper (total in 1 paper)

Communications

Highly efficient synthesis of mononuclear Pt-based carboxylic complexes trans-[Py2Pt(OC(O)R)2] (R = Me, But, Ph)

M. V. Paninaab, N. K. Ogarkovaac, P. V. Dorovatovskiid, O. V. Sulimovaab, E. A. Sosunovab, N. V. Cherkashinaa, J. E. Makarevichab, M. A. Navasardyana, A. S. Popovaa, I. A. Yakusheva

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b Higher Chemical College of the Russian Academy of Sciences, D.I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
d National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
Full-text PDF (470 kB) Citations (1)
Abstract: Two novel synthetic routes were suggested for square-planar carboxylic platinum(ii) complexes with acetic, pivalic, and benzoic ligands. In the first method, heating ionic complex [Py4Pt](OAc)2 under reduced pressure gives a molecular compound trans-[Py2Pt(OAc)2] with a moderate yield. In the second method, the same starting compound [Py4Pt](OAc)2 ∙ 6 H2O is melted with pivalic or benzoic acids, which leads to analogous carboxylic trans-complexes with almost quantitative yields.
Keywords: platinum, synthesis, carboxylate complexes, pyridine, XRD analysis.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (398.5 Kb)


Citation: M. V. Panina, N. K. Ogarkova, P. V. Dorovatovskii, O. V. Sulimova, E. A. Sosunov, N. V. Cherkashina, J. E. Makarevich, M. A. Navasardyan, A. S. Popova, I. A. Yakushev, “Highly efficient synthesis of mononuclear Pt-based carboxylic complexes trans-[Py2Pt(OC(O)R)2] (R = Me, But, Ph)”, Mendeleev Commun., 34:6 (2024), 808–811
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  • https://www.mathnet.ru/eng/mendc/v34/i6/p808
  • This publication is cited in the following 1 articles:
    1. Alexei Zazulya, Semen Berdyugin, Sergey Tkachev, Varvara Lagunova, Dmitriy Sheven, Pavel Abramov, Evgeni Glebov, Danila Vasilchenko, “Preparation of trans,trans-[Pt(py)2(N3)2(OH)2] via Photoinduced Reactivity of [Pt(NO3)6]2– Anion”, Inorg. Chem., 2025  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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