Abstract:
Two novel synthetic routes were suggested for square-planar carboxylic platinum(ii) complexes with acetic, pivalic, and benzoic ligands. In the first method, heating ionic complex [Py4Pt](OAc)2 under reduced pressure gives a molecular compound trans-[Py2Pt(OAc)2] with a moderate yield. In the second method, the same starting compound [Py4Pt](OAc)2 ∙ 6 H2O is melted with pivalic or benzoic acids, which leads to analogous carboxylic trans-complexes with almost quantitative yields.
Citation:
M. V. Panina, N. K. Ogarkova, P. V. Dorovatovskii, O. V. Sulimova, E. A. Sosunov, N. V. Cherkashina, J. E. Makarevich, M. A. Navasardyan, A. S. Popova, I. A. Yakushev, “Highly efficient synthesis of mononuclear Pt-based carboxylic complexes trans-[Py2Pt(OC(O)R)2] (R = Me, But, Ph)”, Mendeleev Commun., 34:6 (2024), 808–811
Linking options:
https://www.mathnet.ru/eng/mendc258
https://www.mathnet.ru/eng/mendc/v34/i6/p808
This publication is cited in the following 1 articles:
Alexei Zazulya, Semen Berdyugin, Sergey Tkachev, Varvara Lagunova, Dmitriy Sheven, Pavel Abramov, Evgeni Glebov, Danila Vasilchenko, “Preparation of trans,trans-[Pt(py)2(N3)2(OH)2] via Photoinduced Reactivity of [Pt(NO3)6]2– Anion”, Inorg. Chem., 2025