Abstract:
Treatment of 1,1-dinitro-1-(3,5-dinitropyrazol-1-yl)methanide with electrophilic fluorinating or difluoroaminating agents affords the corresponding fluorodinitromethyl or (difluoroamino)dinitromethyl pyrazole derivatives. Single crystal X-ray diffraction analysis shows a remarkable high density and DSC exhibits acceptable thermal stability of the compounds.
Citation:
I. L. Dalinger, A. Kh. Shakhnes, K. A. Monogarov, K. Yu. Suponitsky, A. B. Sheremetev, “Novel highly energetic pyrazoles: N-fluorodinitromethyl and N-[(difluoroamino)dinitromethyl] derivatives”, Mendeleev Commun., 25:6 (2015), 429–431
Linking options:
https://www.mathnet.ru/eng/mendc2434
https://www.mathnet.ru/eng/mendc/v25/i6/p429
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