Abstract:
The [3 + 2] cycloaddition of azidofuroxans to internal and terminal acetylenes was found to occur only in ionic liquids on heating and afford (1H-1,2,3-triazol-1-yl)furoxans in moderate to good yields. The reaction with terminal acetylenes proceeds with high regio- selectivity.
Citation:
L. L. Fershtat, S. S. Ashirbaev, A. S. Kulikov, V. V. Kachala, N. N. Makhova, “Ionic liquid-mediated synthesis of (1H-1,2,3-triazol-1-yl)furoxans by [3 + 2] cycloaddition of azidofuroxans to acetylenes”, Mendeleev Commun., 25:4 (2015), 257–259
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