Abstract:
Hydrogenation of phenylacetylene in liquid phase (100–150°C, 6–20bar H2) over FeOx / SiO2 catalysts prepared by thermal decomposition of ammonium trioxalatoferrate affords styrene with selectivities 70–80% depending on temperature and pressure.
Citation:
A. A. Shesterkina, E. V. Shuvalova, E. A. Redina, O. A. Kirichenko, O. P. Tkachenko, I. V. Mishin, L. M. Kustov, “Silica-supported iron oxide nanoparticles: unexpected catalytic activity in hydrogenation of phenylacetylene”, Mendeleev Commun., 27:5 (2017), 512–514
Linking options:
https://www.mathnet.ru/eng/mendc2045
https://www.mathnet.ru/eng/mendc/v27/i5/p512
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O. A. Kirichenko, A. A. Strekalova, G. I. Kapustin, A. A. Shesterkina, “A New Redox Method for Depositing FeOx on the Surface of Pd(0)/SiO2 Nanoparticles—Catalysts for Selective Phenylacetylene Hydrogenation”, Russ. J. Phys. Chem., 92:12 (2018), 2396
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