Abstract:
A combination of Zn–guanidine complex catalyst and biphenyl-4-methanol activator was used as a biofriendly system for the synthesis of poly(d,l-lactide). Kinetic curves of the polymerization were measured by differential scanning calorimetry at various temperatures and concentrations of the activator. Due to an inclusion of guanidine ligands into the polymer chains, the synthesized polylactide is capable of fluorescing.
Citation:
N. G. Sedush, V. V. Izraylit, A. K. Mailyan, D. V. Savinov, Yu. I. Kiryukhin, S. N. Chvalun, “Kinetics of ring-opening polymerization of d,l-lactide catalyzed by functional Zn–guanidine complex with biphenyl-4-methanol activator”, Mendeleev Commun., 27:3 (2017), 281–282
Linking options:
https://www.mathnet.ru/eng/mendc1968
https://www.mathnet.ru/eng/mendc/v27/i3/p281
This publication is cited in the following 9 articles:
S. S. Moskvichev, P. V. Dmitryakov, N. G. Sedush, S. N. Chvalun, “L-Lactide Polymerization Kinetics in the Presence of Ti(Tbse)2 by Differential Scanning Calorimetry”, Russ. J. Phys. Chem. B, 17:4 (2023), 810
S. S. Moskvichev, P. V. Dmitryakov, N. G. Sedush, S. N. Chvalun, “Issledovanie kinetiki polimerizatsii L-laktida v prisutstvii Ti(Tbse)<sub>2</sub> metodom differentsialnoi skaniruyuschei kalorimetrii”, Himičeskaâ fizika, 42:7 (2023), 33
O. V. Arzhakova, M. S. Arzhakov, E. R. Badamshina, E. V. Bryuzgin, E. B. Bryuzgina, A. V. Bystrova, G. V. Vaganov, V. V. Vasilevskaya, A. Yu. Vdovichenko, M. O. Gallyamov, R. A. Gumerov, A. L. Didenko, V. V. Zefirov, S. V. Karpov, P. V. Komarov, V. G. Kulichikhin, S. A. Kurochkin, S. V. Larin, A. Ya. Malkin, S. A. Milenin, A. M. Muzafarov, V. S. Molchanov, A. V. Navrotskiy, I. A. Novakov, E. F. Panarin, I. G. Panova, I. I. Potemkin, V. M. Svetlichnyi, N. G. Sedush, O. A. Serenko, S. A. Uspenskii, O. E. Philippova, A. R. Khokhlov, S. N. Chvalun, S. S. Sheiko, A. V. Shibaev, I. V. Elmanovich, V. E. Yudin, A. V. Yakimanskii, A. A. Yaroslavov, “Polymers for the future”, Russian Chem. Reviews, 91:12 (2022), RCR5062
V. A. Demina, N. G. Sedush, E. N. Goncharov, S. V. Krasheninnikov, A. E. Krupnin, N. G. Goncharov, S. N. Chvalun, “Biodegradable Nanostructured Composites for Surgery and Regenerative Medicine”, Nanotechnol Russia, 16:1 (2021), 2
N. G. Sedush, Y. A. Kadina, E. V. Razuvaeva, A. A. Puchkov, E. M. Shirokova, V. I. Gomzyak, K. T. Kalinin, A. I. Kulebyakina, S. N. Chvalun, “Nanoformulations of Drugs Based on Biodegradable Lactide Copolymers with Various Molecular Structures and Architectures”, Nanotechnol Russia, 16:4 (2021), 421
Kirill T. Kalinin, Nikita G. Sedush, Petr V. Dmitryakov, Sergei N. Chvalun, “Kinetics of D,L–Lactide Polymerization Initiated with Zirconium Acetylacetonate”, ChemistryOpen, 9:10 (2020), 1027
Thomas Rösener, Konstantin Kröckert, Alexander Hoffmann, Sonja Herres‐Pawlis, “The Curious Case of a Phenylated Guanidinoquinoline Ligand: Synthesis, Complexes and ATRP Properties of DMEG6phqu”, Zeitschrift anorg allge chemie, 644:21 (2018), 1317
Thomas Rösener, Alexander Hoffmann, Sonja Herres‐Pawlis, “Next Generation of Guanidine Quinoline Copper Complexes for Highly Controlled ATRP: Influence of Backbone Substitution on Redox Chemistry and Solubility”, Eur J Inorg Chem, 2018:27 (2018), 3164
B. A. Lozhkin, A. V. Shlyakhtin, V. V. Bagrov, P. V. Ivchenko, I. E. Nifant'ev, “Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization”, Mendeleev Commun., 28:1 (2018), 61–63
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