A. N. Vereshchagin, K. A. Karpenko, M. N. Elinson, E. O. Dorofeeva, A. S. Goloveshkin, M. P. Egorov, “Pseudo six-component stereoselective synthesis of 2,4,6-triaryl-3,3,5,5-tetracyanopiperidines”, Mendeleev Commun., 28:4 (2018), 384

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Mendeleev Communications, 2018, Volume 28, Issue 4, Pages 384–386
DOI: https://doi.org/10.1016/j.mencom.2018.07.014 (Mi mendc1774)

This article is cited in 16 scientific papers (total in 16 papers)

Communications

Pseudo six-component stereoselective synthesis of 2,4,6-triaryl-3,3,5,5-tetracyanopiperidines

A. N. Vereshchagin^a, K. A. Karpenko^a, M. N. Elinson^a, E. O. Dorofeeva^a, A. S. Goloveshkin^b, M. P. Egorov^a

^a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Full-text PDF (466 kB) Citations (16)

DOI: https://doi.org/10.1016/j.mencom.2018.07.014

Graphic abstract: Pseudo six-component stereoselective synthesis of 2,4,6-triaryl-3,3,5,5-tetracyanopiperidines

Abstract: The Knövenagel–Michael–Mannich cascade reaction of aromatic aldehyde (3 equiv.), malononitrile (2 equiv.) and ammonium acetate or aqueous ammonia provides convenient stereoselective access to cis,cis-2,4,6-triaryl-3,3,5,5-tetracyanopiperidines in 62–94% yields. Six new bonds form as a result of the domino process, ammonium acetate serving as a nitrogen source.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(305.7 Kb)

Citation: A. N. Vereshchagin, K. A. Karpenko, M. N. Elinson, E. O. Dorofeeva, A. S. Goloveshkin, M. P. Egorov, “Pseudo six-component stereoselective synthesis of 2,4,6-triaryl-3,3,5,5-tetracyanopiperidines”, Mendeleev Commun., 28:4 (2018), 384–386

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https://www.mathnet.ru/eng/mendc/v28/i4/p384

This publication is cited in the following 16 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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