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Mendeleev Communications, 2019, Volume 29, Issue 5, Pages 486–488
DOI: https://doi.org/10.1016/j.mencom.2019.09.002
(Mi mendc1565)
 

This article is cited in 4 scientific papers (total in 4 papers)

Communications

Size effect in nonstoichiometric titanium monoxide and vanadium carbide nanocrystals measured by positron lifetime spectroscopy

A. A. Rempelabc, A. A. Valeevabc, A. S. Kurlovb, G. Klinserd, W. Sprengeld

a Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
b Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
c NANOTECH Centre, Ural Federal University, Ekaterinburg, Russian Federation
d Institute of Materials Physics, Graz University of Technology, Graz, Austria
Full-text PDF (364 kB) Citations (4)
Abstract: A size effect in nonstoichiometric titanium monoxide TiOy and vanadium carbide VCy nanocrystals containing high concentrations of structural vacancies was detected by electron-positron annihilation. The effect consists of a considerable increase in the positron lifetime with the specific surface area. An analysis of the intensity of a long lifetime surface component in the positron annihilation spectra and the average positron lifetime for different nonstoichiometric compounds indicated a universal character of the observed size effect.
Document Type: Article
Language: English


Citation: A. A. Rempel, A. A. Valeeva, A. S. Kurlov, G. Klinser, W. Sprengel, “Size effect in nonstoichiometric titanium monoxide and vanadium carbide nanocrystals measured by positron lifetime spectroscopy”, Mendeleev Commun., 29:5 (2019), 486–488
Linking options:
  • https://www.mathnet.ru/eng/mendc1565
  • https://www.mathnet.ru/eng/mendc/v29/i5/p486
  • This publication is cited in the following 4 articles:
    1. Rafał Idczak, Piotr Sobota, Lan Maria Tran, Michał Babij, Karolina Idczak, Wojciech Nowak, Adam Pikul, “New Route to Synthesize High-Entropy Carbide Powders by Mechanical Alloying”, Metall Mater Trans A, 55:2 (2024), 523  crossref
    2. M.I. Chebanenko, D.P. Danilovich, A.A. Lobinsky, V.I. Popkov, A.A. Rempel, A.A. Valeeva, “Novel high stable electrocatalyst based on non-stoichiometric nanocrystalline niobium carbide toward effective hydrogen evolution”, International Journal of Hydrogen Energy, 46:32 (2021), 16907  crossref
    3. A. A. Valeeva, A. A. Rempel, S. V. Rempel', S. I. Sadovnikov, A. I. Gusev, “Nonstoichiometry, structure and properties of nanocrystalline oxides, carbides and sulfides”, Russian Chem. Reviews, 90:5 (2021), 601–626  mathnet  mathnet  crossref  isi  scopus
    4. Svetlana V. Rempel, Andrey A. Rempel, Albina A. Valeeva, “Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy”, ACS Omega, 5:35 (2020), 22513  crossref
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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