Abstract:
Pyridinium bromide has been tested as a new mediator for electrochemical synthesis of functionalized cyclopropane from alkylidenemalononitriles and CH-acids. The process was performed in an undivided cell with the use of substoichiometric amount of PyHBr that serves both as a mediator and a supporting electrolyte, and MeOH or MeCN as the solvents.
Citation:
A. N. Vereshchagin, E. O. Dorofeeva, M. N. Elinson, V. A. Korolev, M. P. Egorov, “Pyridinium bromide as a new mediator for electrochemical transformations involving CH-acids”, Mendeleev Commun., 29:4 (2019), 391–392
Linking options:
https://www.mathnet.ru/eng/mendc1533
https://www.mathnet.ru/eng/mendc/v29/i4/p391
This publication is cited in the following 2 articles:
Anastasiya I. Ershova, Oleg E. Nasakin, Oleg V. Ershov, “One-pot transformations of tetracyanocyclopropanes into highly functionalized pyridines”, Chem Heterocycl Comp, 59:8 (2023), 610
Michail N. Elinson, Anatoly N. Vereshchagin, Yuliya E. Ryzhkova, Mikhail P. Egorov, “Selective and efficient electrocatalytic way to spirobarbituric dihydrofurans”, Mendeleev Communications, 31:3 (2021), 347
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