Abstract:
The trans-etherification of 4,6-di-tert-butyl-2,3-dihydroxybenzyl methyl ether with α,ω-alkanediols under mild conditions (CHCl3, 65°C) leads to new sterically hindered biscatechols in high yields. The molecular structures of three of them was determined by single-crystal X-ray diffraction.
Citation:
E. R. Zhiganshina, M. V. Arsenyev, A. S. Shavyrin, E. V. Baranov, S. A. Chesnokov, “Trans-etherification of catechol-type benzylic ether with diols as a route to new sterically hindered bis-catechols”, Mendeleev Commun., 29:1 (2019), 91–93
Linking options:
https://www.mathnet.ru/eng/mendc1433
https://www.mathnet.ru/eng/mendc/v29/i1/p91
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