Abstract:
Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH4I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety.
Citation:
A. O. Terent'ev, O. M. Mulina, A. I. Ilovaisky, V. A. Kokorekin, G. I. Nikishin, “Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols”, Mendeleev Commun., 29:1 (2019), 80–82
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https://www.mathnet.ru/eng/mendc1429
https://www.mathnet.ru/eng/mendc/v29/i1/p80
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