N. A. Kuznetsov, O. A. Bogomolova, I. A. Koblov, A. V. Samet, V. V. Semenov, “Synthesis of 3,4-diarylisoxazoline N-oxides from nitrostilbenes and nitroacetates”, Mendeleev Commun., 35:1 (2025), 22

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Mendeleev Communications, 2025, Volume 35, Issue 1, Pages 22–23
DOI: https://doi.org/10.71267/mencom.7584 (Mi mendc1346)

Communications

Synthesis of 3,4-diarylisoxazoline N-oxides from nitrostilbenes and nitroacetates

N. A. Kuznetsov^ab, O. A. Bogomolova^b, I. A. Koblov^a, A. V. Samet^a, V. V. Semenov^a

^a N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
^b D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7584

Graphic abstract: Synthesis of 3,4-diarylisoxazoline <em>N</em>-oxides from nitrostilbenes and nitroacetates

Abstract: A base-catalyzed reaction of nitrostilbenes with alkyl nitroacetates proceeds regioselectively to afford 3,4-diarylisoxazoline N-oxides as sole or major products. In some cases small amounts of 4,5-diarylisoxazoline N-oxides were formed as side products.

Keywords: nitrostilbenes, alkyl nitroacetates, 3,4-diarylisoxazoline N-oxides, 4,5-diarylisoxazoline N-oxides, pyridinium ylides.

Funding agency	Grant number
Russian Science Foundation	24-23-00109

Received: 05.08.2024
Accepted: 11.09.2024

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(871.6 Kb)

Citation: N. A. Kuznetsov, O. A. Bogomolova, I. A. Koblov, A. V. Samet, V. V. Semenov, “Synthesis of 3,4-diarylisoxazoline N-oxides from nitrostilbenes and nitroacetates”, Mendeleev Commun., 35:1 (2025), 22–23

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Citing articles in Google Scholar: Russian citations, English citations
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Abstract page:	107
Full-text PDF :	8
References:	16
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