M. Yu. Zaremski, E. E. Aliev, E. S. Garina, N. S. Melik-Nubarov, “TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer”, Mendeleev Commun., 30:5 (2020), 627

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Mendeleev Communications, 2020, Volume 30, Issue 5, Pages 627–629
DOI: https://doi.org/10.1016/j.mencom.2020.09.025 (Mi mendc1274)

This article is cited in 1 scientific paper (total in 1 paper)

Communications

TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer

M. Yu. Zaremski, E. E. Aliev, E. S. Garina, N. S. Melik-Nubarov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (309 kB) Citations (1)

DOI: https://doi.org/10.1016/j.mencom.2020.09.025

Graphic abstract: TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer

Abstract: A new synthesis of poly(methyl methacrylate) vinylterminated macromonomer is performed using the disproportionation between propagating methyl methacrylate radical and nitroxide TEMPO. The ability of the macromonomer to polymerize and copolymerize with styrene and poly(ethylene glycol) methacrylate was confirmed by GPC and isothermal calorimetry.

Keywords: macromonomers, nitroxides, radical polymerization, poly(methyl methacrylate), disproportionation, terminal vinyl group, brush-like copolymers.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(591.9 Kb)

Citation: M. Yu. Zaremski, E. E. Aliev, E. S. Garina, N. S. Melik-Nubarov, “TEMPO-mediated radical polymerization in the synthesis of poly(methyl methacrylate) macromonomer”, Mendeleev Commun., 30:5 (2020), 627–629

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https://www.mathnet.ru/eng/mendc1274

https://www.mathnet.ru/eng/mendc/v30/i5/p627

This publication is cited in the following 1 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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