Abstract:
Estimation of the influence of molecular substituents on electroluminescence and electron–hole mobility in copolyfluorenes with the use of a CELIV technique has revealed that minor changes in the number of benzothiadiazole fragments in copolyfluorenes has a dramatic effect on the optoelectronic properties of these polymers to improve the electroluminescence and electron mobility by factors of 20 and 10, respectively.
Keywords:
Random copolymers, Fluorescence, PLEDs, CELIV, Electron–hole mobility.
Citation:
D. A. Lypenko, G. I. Nosova, I. A. Berezin, A. R. Tameev, E. I. Mal'tsev, “Role of benzothiadiazole substituents in white electroluminescent single macromolecules of fluorene-based copolymers”, Mendeleev Commun., 30:2 (2020), 165–167
Linking options:
https://www.mathnet.ru/eng/mendc1135
https://www.mathnet.ru/eng/mendc/v30/i2/p165
This publication is cited in the following 2 articles:
A. A. Yakimanskiy, A. M. Mitroshin, T. G. Chulkova, S. A. Miltsov, A. V. Yakimanskii, “Fluorene-based π-conjugated polymers for OLEDs: advances, opportunities, and challenges”, Mendeleev Commun., 34:5 (2024), 609–629
Pavel S. Gribanov, Dmitry A. Loginov, Dmitry A. Lypenko, Artem V. Dmitriev, Sergey I. Pozin, Alexey E. Aleksandrov, Alexey R. Tameev, Igor L. Martynov, Andrey Yu. Chernyadyev, Sergey N. Osipov, “New Unsymmetrically Substituted Benzothiadiazole-Based Luminophores: Synthesis, Optical, Electrochemical Studies, Charge Transport, and Electroluminescent Characteristics”, Molecules, 26:24 (2021), 7596